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• W2000777627 abstract "A vibrating sample magnetometer (VSM) has been used to study the field-dependent magnetization, M(H), of the d5−d7 metal acetates [M(OAc)2.nH2O], metal β−diketonate complexes [M(tba)2(H2O)2] and the macromolecular polymers [M(tba)2(4,4-bipy)]n (where, M = Mn(II), Fe(II), and Co(II), OAc = O2CCH3, tba = deprotonated 3-benzoyl-1.1.1-trifluoroacetone, and 4,4-bipy = 4,4′-bipyridine). The magnetic field strength (H) was applied in the range of 0−104 Oe at ambient temperature (ca. 23°C). The experimental results showed that the d5−d7 metal acetate, complexes and polymers exhibit low paramagnetic properties excepting [Fe(tba)2(4,4-bipy)]n polymer, which had negative magnetization M(emu/g) showing diamagnetic properties in the range 0−104 Oe. The magnetization was almost equal to zero without an applied magnetic field (H(Oe)) for each d5−d7 metal acetate, complex, and polymer. The linear M(H) curve had a magnetic saturation for iron and manganese acetate species at the magnetic field strengths of 3.1 × 103 and 4.7 × 103 Oe, respectively. The external magnetic field reached 9.0 × 103 Oe without any saturation magnetization for the cobalt compounds. The coordination effect of 3-benzoyl-1.1.1-trifluoroacetone (H-tba) and 4,4′-bipyridine (4,4′-bipy) ligands on the field-dependent magnetization M(H) and paramagnetic behavior of d5−d7 metal atoms is discussed. The field-dependent magnetization M(H) curves of metal β−diketonate complexes and the polymers including d5−d7 metal acetates showed a weak field octahedral geometry." @default.
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• W2000777627 date "2014-06-25" @default.
• W2000777627 modified "2023-09-23" @default.
• W2000777627 title "The Field-Dependent Magnetization of<i>d⁵</i>–<i>d⁷</i>Metal β−Diketonate Complexes and Their Macromolecular Polymers" @default.
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• W2000777627 doi "https://doi.org/10.1080/00222348.2014.901872" @default.
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