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- W2000780333 abstract "The hydrated carborane acid H(CHB11I11)·8H2O crystallizes in nanometer-diameter tubes of Haq+ enclosed by walls of carborane anions. Three different types of Haq+ clusters are found in these tubes: a symmetrical H13O6+ ion with an unusually elongated Zundel-type H5O2+ core, two hydrated H7O3+ ions, and an unprecedented H17O8+ ion having a nearly square core. All of the Haq+ cations show unexpectedly longer O···O separations than in discrete Haq+ ions, indicating greater delocalization of positive charge. The centrosymmetric Haq+ ions are linked via short H bonds, forming a true one-dimensional proton wire." @default.
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- W2000780333 date "2009-11-13" @default.
- W2000780333 modified "2023-10-17" @default.
- W2000780333 title "H<sub>aq</sub><sup>+</sup> Structures in Proton Wires inside Nanotubes" @default.
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- W2000780333 doi "https://doi.org/10.1021/ja907708g" @default.
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