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- W2000781578 abstract "Laser light scattering (LLS) techniques were used to characterize the micellization of poly(d,l-lactide)–poly(ethylene glycol)–poly(d,l-lactide) (LEL) triblock copolymer (MW 1K–2K–1K) in aqueous solution. We observed the existence of both thermodynamically stable flower-like micelles (regular micelles) and large, less soluble nanoparticles (irregular micelles) in dilute aqueous solutions with the same preparation procedure. Both kinds of micelles were found to co-exist with single copolymer chains. The initial copolymer concentration determines the nature of the micelles. The regular core-shell micelle formation follows a closed association mechanism, resulting in flower-like micelles. The hydrophobicity of a L unit is estimated as ∼0.5–0.6 B (polyoxybutylene) units from the micellization parameters, which is quite consistent with earlier estimations obtained from EL diblock copolymers." @default.
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- W2000781578 date "2004-10-01" @default.
- W2000781578 modified "2023-09-29" @default.
- W2000781578 title "Regular and irregular micelles formed by A LEL triblock copolymer in aqueous solution" @default.
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- W2000781578 doi "https://doi.org/10.1016/j.polymer.2004.08.074" @default.
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