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- W2000783837 abstract "The structure of malformin A1, a metabolic product of Aspergillus niger, was reexamined and the sequence of its amino acid constituents established as The cyclopentapeptide-disulfide corresponding to this structure was prepared through stepwise synthesis of the protected pentapeptide derivative, benzyloxy-carbonyl-l-isoleucyl-S-benzyl-d-cysteinyl-S-benzyl-d-cysteinyl-l-valyl-d-leucine methylester, which in turn was converted to the hydrazide, partially deprotected, and cyclized via the azide. On removal of the S-benzyl groups and oxidation to the disulfide, a synthetic material was obtained that was indistinguishable from natural malformin A1 and was as equally potent in causing curvatures on corn roots." @default.
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- W2000783837 title "Structure and synthesis of malformin A1" @default.
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- W2000783837 doi "https://doi.org/10.1016/0045-2068(75)90029-2" @default.
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