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- W2000785443 abstract "A combination of ab initio R-matrix techniques and multi-channel quantum defect theory (R-matrix/MQDT method), previously formulated in part I of this project, is used to analyse resonant changes in the MQDT scattering matrix arising from valence state interactions with the Rydberg channels. Results for NO are reported for six l channels associated with the lowest,1Σ+, target channels of NO+. The resonant couplings between the Rydberg channels and four valence states, I (2Σ+), B (2 2Π), L (3 2Π), 4 2Π and , are shown to vary sufficiently smoothly with both bond length and energy to allow easy interpolation. The coupling constants between p π Rydberg and the B valence states are in good agreement with the experimental data of Gallusser and Dressler. Sets of interacting potential curves for states of symmetries 2Σ+,2Π and 2Δ are reconstructed from the MQDT K-matrix data." @default.
- W2000785443 created "2016-06-24" @default.
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- W2000785443 date "2003-10-28" @default.
- W2000785443 modified "2023-10-16" @default.
- W2000785443 title "Ab initio R-matrix/multi-channel quantum defect theory study of nitric oxide: II. Analysis of valence/Rydberg interactions" @default.
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- W2000785443 doi "https://doi.org/10.1088/0953-4075/36/22/014" @default.
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