Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000791348> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2000791348 endingPage "102" @default.
- W2000791348 startingPage "99" @default.
- W2000791348 abstract "According to the relative locations of the R and S stereogenic centres in the diamine chelate, the kinetically labile complex (+)-[Pd{(S)- CH3CH(1-C10H6)NMe2-C2,N}{(R,S)-Me2NCH(Me)CH(Me)NMe2-N,N′}]ClO4 exists as an equilibrium mixture of two stereochemically distinct isomers in solution. The equilibrium ratio is temperature and solvent dependent. In d2-dichloromethane, the minor isomer observed at room temperature diminishes when the temperature is lowered to −20°C. A low temperature 2-D ROESY NMR experiment is used to identify the sterically favored major isomer in solution and hence to evaluate the efficiency of the chiral inductive effects of coordinated (S)-dimethyl(1-(α-naphthyl)ethyl)amine." @default.
- W2000791348 created "2016-06-24" @default.
- W2000791348 creator A5008659345 @default.
- W2000791348 creator A5050160701 @default.
- W2000791348 creator A5073696111 @default.
- W2000791348 creator A5083759083 @default.
- W2000791348 date "1999-01-01" @default.
- W2000791348 modified "2023-09-27" @default.
- W2000791348 title "Stereochemical investigation of a kinetically labile chiral organopalladium complex in solution" @default.
- W2000791348 cites W1991306011 @default.
- W2000791348 cites W1999001149 @default.
- W2000791348 cites W2000546166 @default.
- W2000791348 cites W2001009713 @default.
- W2000791348 cites W2006766104 @default.
- W2000791348 cites W2008574838 @default.
- W2000791348 cites W2010231909 @default.
- W2000791348 cites W2014481543 @default.
- W2000791348 cites W2016129024 @default.
- W2000791348 cites W2021599578 @default.
- W2000791348 cites W2053087280 @default.
- W2000791348 cites W2055730023 @default.
- W2000791348 cites W2062363981 @default.
- W2000791348 cites W2078020394 @default.
- W2000791348 cites W2097664718 @default.
- W2000791348 cites W2114828929 @default.
- W2000791348 cites W2164756275 @default.
- W2000791348 cites W2950842096 @default.
- W2000791348 doi "https://doi.org/10.1016/s0020-1693(98)00262-x" @default.
- W2000791348 hasPublicationYear "1999" @default.
- W2000791348 type Work @default.
- W2000791348 sameAs 2000791348 @default.
- W2000791348 citedByCount "5" @default.
- W2000791348 countsByYear W20007913482015 @default.
- W2000791348 crossrefType "journal-article" @default.
- W2000791348 hasAuthorship W2000791348A5008659345 @default.
- W2000791348 hasAuthorship W2000791348A5050160701 @default.
- W2000791348 hasAuthorship W2000791348A5073696111 @default.
- W2000791348 hasAuthorship W2000791348A5083759083 @default.
- W2000791348 hasConcept C131779359 @default.
- W2000791348 hasConcept C134195300 @default.
- W2000791348 hasConcept C146686406 @default.
- W2000791348 hasConcept C155647269 @default.
- W2000791348 hasConcept C161790260 @default.
- W2000791348 hasConcept C178790620 @default.
- W2000791348 hasConcept C185592680 @default.
- W2000791348 hasConcept C201194858 @default.
- W2000791348 hasConcept C2779348916 @default.
- W2000791348 hasConcept C2780400988 @default.
- W2000791348 hasConcept C2780471494 @default.
- W2000791348 hasConcept C2780871995 @default.
- W2000791348 hasConcept C502130503 @default.
- W2000791348 hasConcept C71240020 @default.
- W2000791348 hasConceptScore W2000791348C131779359 @default.
- W2000791348 hasConceptScore W2000791348C134195300 @default.
- W2000791348 hasConceptScore W2000791348C146686406 @default.
- W2000791348 hasConceptScore W2000791348C155647269 @default.
- W2000791348 hasConceptScore W2000791348C161790260 @default.
- W2000791348 hasConceptScore W2000791348C178790620 @default.
- W2000791348 hasConceptScore W2000791348C185592680 @default.
- W2000791348 hasConceptScore W2000791348C201194858 @default.
- W2000791348 hasConceptScore W2000791348C2779348916 @default.
- W2000791348 hasConceptScore W2000791348C2780400988 @default.
- W2000791348 hasConceptScore W2000791348C2780471494 @default.
- W2000791348 hasConceptScore W2000791348C2780871995 @default.
- W2000791348 hasConceptScore W2000791348C502130503 @default.
- W2000791348 hasConceptScore W2000791348C71240020 @default.
- W2000791348 hasIssue "1" @default.
- W2000791348 hasLocation W20007913481 @default.
- W2000791348 hasOpenAccess W2000791348 @default.
- W2000791348 hasPrimaryLocation W20007913481 @default.
- W2000791348 hasRelatedWork W2000791348 @default.
- W2000791348 hasRelatedWork W2004681263 @default.
- W2000791348 hasRelatedWork W2014789700 @default.
- W2000791348 hasRelatedWork W2042361045 @default.
- W2000791348 hasRelatedWork W2148648077 @default.
- W2000791348 hasRelatedWork W2950173770 @default.
- W2000791348 hasRelatedWork W2952015118 @default.
- W2000791348 hasRelatedWork W3034897343 @default.
- W2000791348 hasRelatedWork W311764173 @default.
- W2000791348 hasRelatedWork W4206601570 @default.
- W2000791348 hasVolume "284" @default.
- W2000791348 isParatext "false" @default.
- W2000791348 isRetracted "false" @default.
- W2000791348 magId "2000791348" @default.
- W2000791348 workType "article" @default.