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- W2000796810 abstract "Abstract Synthesis gas production by partial oxidation of methane (POM) (CH4/O2 = 1.8–4.5/1) at 850–960 °C over NdCaCoO3.96 was investigated using a fixed bed flow-type reactor. The NdCaCoO3.96-derived catalyst demonstrated conversion of CH4 and O2 up to 90% while CO and H2 selectivities were over 90% at a H2/CO ratio ∼2. The decomposition of NdCaCoO3.96 at POM conditions results in the formation of finely dispersed Nd2O3, CaO, cobalt oxides and cobalt metal. The as-prepared catalyst exhibited excellent stability of the catalytic properties, and no activity decrease was observed for 140 h of reaction. Synthesis gas formation was accompanied by carbon deposition on the catalyst. However, this process has little or no influence on the catalytic properties of the material." @default.
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- W2000796810 date "2015-01-01" @default.
- W2000796810 modified "2023-10-10" @default.
- W2000796810 title "Partial oxidation of methane to produce syngas over a neodymium–calcium cobaltate-based catalyst" @default.
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- W2000796810 doi "https://doi.org/10.1016/j.apcata.2014.10.027" @default.
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