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- W2000797308 abstract "Complexes of the general formula [M(CO)5L](M = Cr or W; L = [graphic omitted]H2,[graphic omitted]H2, and β-[graphic omitted]HME) have been prepared and studied by variable-temperature 1H n.m.r. spectroscopy. Detailed computer syntheses of static and dynamic spectra indicate that the complexes exist in a number of conformations which are interconverted by fluxional processes. These processes are six-membered ligand ring reversal, pyramidal sulphur-atom inversion, and commutation of an M(CO)5 moiety over three sulphur atoms via a 1,3-shift process. Accurate energy barriers (ΔG‡) for all three processes have been calculated. It is interesting to note that only the β-[graphic omitted]HMe complexes undergo the 1,3-shift process at ambient temperature." @default.
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- W2000797308 date "1981-01-01" @default.
- W2000797308 modified "2023-09-26" @default.
- W2000797308 title "Ring reversal, sulphur inversion, and 1,3-metal shifts in sulphur-containing six-membered-ring complexes of chromium and tungsten carbonyls" @default.
- W2000797308 doi "https://doi.org/10.1039/dt9810001944" @default.
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