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- W2000797882 abstract "Novel 10-membered pyrimidine enediynes (3 and 4) were synthesized in seven and eight steps, respectively. These compounds were compared for their abilities to undergo Bergman cyclization both thermally and photochemically. Alcohol 3 readily cyclized both thermally and photochemically in iPrOH, while ketone 4 only showed efficient thermal cyclization. Both compounds were also shown to cleave dsDNA under the appropriate conditions." @default.
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- W2000797882 date "2000-11-01" @default.
- W2000797882 modified "2023-10-16" @default.
- W2000797882 title "Photochemical and Thermal Bergman Cyclization of a Pyrimidine Enediynol and Enediynone" @default.
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- W2000797882 doi "https://doi.org/10.1021/ol006061j" @default.
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