Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000800394> ?p ?o ?g. }
- W2000800394 endingPage "1419" @default.
- W2000800394 startingPage "1403" @default.
- W2000800394 abstract "Nanostructured conducting polymeric materials are of exceptional interest due to their potential applications in sensors, actuators, transistors and displays. Arguably the most promising method for synthesizing polyaniline nanostructures is self-assembly, which is very advantageous in its simplicity and volume. However, this self-assembly remains only partly understood, with a number of already established models (a “micelle theory” and a “phenazine theory”) at odds with more recent discoveries (nanosheet curling and nanoparticle agglomeration), leading to a fragmented understanding of this important topic. In this paper we address this problem in two ways. First, we review the aforementioned older models and recent discoveries. Second, we propose an expanded polyaniline nanostructure self-assembly model – “Multi-Layer Theory” – that goes beyond the scope of existing theories, thereby accommodating the more recent discoveries. The expanded synthesis framework we present is based on a multi-layered approach incorporating intrinsic morphologies. The three proposed intrinsic morphologies underpinning our model are nanofibrils, nanosheets and nanoparticles; the forces driving their subsequent self-assembly interactions are mainly π–π stacking, hydrogen bonding and charge–charge repulsion from protonation. These interactions between the three intrinsic morphologies give rise to observed growth, agglomeration and curling behaviours that ultimately generate complex multi-layered nanostructures such as double-walled conducting polymer nanotubes." @default.
- W2000800394 created "2016-06-24" @default.
- W2000800394 creator A5020347994 @default.
- W2000800394 creator A5031490064 @default.
- W2000800394 creator A5080064818 @default.
- W2000800394 date "2010-12-01" @default.
- W2000800394 modified "2023-10-06" @default.
- W2000800394 title "Theories of polyaniline nanostructure self-assembly: Towards an expanded, comprehensive Multi-Layer Theory (MLT)" @default.
- W2000800394 cites W172532486 @default.
- W2000800394 cites W1965153145 @default.
- W2000800394 cites W1966073340 @default.
- W2000800394 cites W1968066819 @default.
- W2000800394 cites W1970314349 @default.
- W2000800394 cites W1973048245 @default.
- W2000800394 cites W1974167130 @default.
- W2000800394 cites W1974788729 @default.
- W2000800394 cites W1976250840 @default.
- W2000800394 cites W1976671961 @default.
- W2000800394 cites W1978338749 @default.
- W2000800394 cites W1978620861 @default.
- W2000800394 cites W1979880909 @default.
- W2000800394 cites W1979981709 @default.
- W2000800394 cites W1980516378 @default.
- W2000800394 cites W1981193833 @default.
- W2000800394 cites W1981563031 @default.
- W2000800394 cites W1984104581 @default.
- W2000800394 cites W1985149935 @default.
- W2000800394 cites W1985491236 @default.
- W2000800394 cites W1986520320 @default.
- W2000800394 cites W1987325746 @default.
- W2000800394 cites W1988310931 @default.
- W2000800394 cites W1991117333 @default.
- W2000800394 cites W1992267536 @default.
- W2000800394 cites W1992895341 @default.
- W2000800394 cites W1994651370 @default.
- W2000800394 cites W1994654177 @default.
- W2000800394 cites W1996807980 @default.
- W2000800394 cites W1997193020 @default.
- W2000800394 cites W1997495589 @default.
- W2000800394 cites W1998179773 @default.
- W2000800394 cites W1998641799 @default.
- W2000800394 cites W1999332606 @default.
- W2000800394 cites W1999823482 @default.
- W2000800394 cites W2001117009 @default.
- W2000800394 cites W2001889570 @default.
- W2000800394 cites W2008991690 @default.
- W2000800394 cites W2010076394 @default.
- W2000800394 cites W2011828628 @default.
- W2000800394 cites W2012309802 @default.
- W2000800394 cites W2012394500 @default.
- W2000800394 cites W2012866734 @default.
- W2000800394 cites W2013747064 @default.
- W2000800394 cites W2017970648 @default.
- W2000800394 cites W2020594991 @default.
- W2000800394 cites W2020661987 @default.
- W2000800394 cites W2021660705 @default.
- W2000800394 cites W2021775474 @default.
- W2000800394 cites W2021838640 @default.
- W2000800394 cites W2021882290 @default.
- W2000800394 cites W2024145783 @default.
- W2000800394 cites W2024369238 @default.
- W2000800394 cites W2024423094 @default.
- W2000800394 cites W2026448047 @default.
- W2000800394 cites W2027071441 @default.
- W2000800394 cites W2027598903 @default.
- W2000800394 cites W2029018319 @default.
- W2000800394 cites W2029694117 @default.
- W2000800394 cites W2030606702 @default.
- W2000800394 cites W2031380740 @default.
- W2000800394 cites W2031763203 @default.
- W2000800394 cites W2033598182 @default.
- W2000800394 cites W2034137807 @default.
- W2000800394 cites W2034177207 @default.
- W2000800394 cites W2034513135 @default.
- W2000800394 cites W2034734459 @default.
- W2000800394 cites W2034995459 @default.
- W2000800394 cites W2036612422 @default.
- W2000800394 cites W2036690884 @default.
- W2000800394 cites W2037529652 @default.
- W2000800394 cites W2038764231 @default.
- W2000800394 cites W2039442220 @default.
- W2000800394 cites W2039533872 @default.
- W2000800394 cites W2039566463 @default.
- W2000800394 cites W2040742863 @default.
- W2000800394 cites W2041821529 @default.
- W2000800394 cites W2044452139 @default.
- W2000800394 cites W2044811829 @default.
- W2000800394 cites W2045743618 @default.
- W2000800394 cites W2047408700 @default.
- W2000800394 cites W2048368153 @default.
- W2000800394 cites W2049324404 @default.
- W2000800394 cites W2055862679 @default.
- W2000800394 cites W2056852321 @default.
- W2000800394 cites W2057912202 @default.
- W2000800394 cites W2058657344 @default.
- W2000800394 cites W2060713410 @default.
- W2000800394 cites W2060955646 @default.
- W2000800394 cites W2062635245 @default.