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- W2000800774 abstract "The stereochemical configuration of hydroxylated products of docosahexaenoic acid (22:6w3) formed by human platelets and rat brain homogenate were characterized for the first time. Chiral phase HPLC was employed along with autooxidized 22:6w3 as reference material. The 14- and 11-hydroxy 22:6w3 (HDHE) products produced by human platelets were in the S configuration. Rat brain homogenate produced all of the ten possible positional isomers when incubated with 22:6w3. Their retention behavior on the reversed and chiral phase HPLC columns and GC/MS/EI analysis indicated that they were 20-, 17-, 16-, 14-, 13-, 11-, 10-, 8-, 7- and 4-HDHE. However, stereochemical analysis revealed that each positional isomer was a racemic mixture, suggesting that these were not formed by lipoxygenation but mainly by peroxidation process." @default.
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- W2000800774 date "1990-11-01" @default.
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- W2000800774 title "Sterochemical analysis of hydroxylated docosahexaenoates produced by human platelets and rat brain homogenate" @default.
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- W2000800774 doi "https://doi.org/10.1016/0090-6980(90)90110-h" @default.
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