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- W2000802505 abstract "Cyclic voltammograms of (OH)2HfPc(Cl) and (OH)2ZrPc(Cl) (Pc(-2) = phthalocyanine dianion) show one oxidation couple and two reduction couples in the presence of a variety of solvent-electrolyte systems. All redox processes are centred on the phthalocyanine ring rather than the metal. The first oxidation occurs at the phthalocyanine ligand to give [HfPc(-1)]·+ and [ZrPc(-1)]·+ π cation radical complexes. The two reduction couples correspond to the successive one-electron reductions of the phthalocyanine ligand to give MPc(-3)·− and MPc(-4)2− species. A third reduction couple, observed only for solutions (OH)2HfPc(Cl) in dimethyl sulfoxide, is assigned to further reduction of the ring and the formation of the HfPc(-5)·3− species." @default.
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- W2000802505 date "1994-09-01" @default.
- W2000802505 modified "2023-09-27" @default.
- W2000802505 title "Cyclic voltammetric studies of hafnium and zirconium phthalocyanines" @default.
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- W2000802505 doi "https://doi.org/10.1016/0379-6779(94)90086-8" @default.
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