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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000803578> ?p ?o ?g. }

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• W2000803578 startingPage "5978" @default.
• W2000803578 abstract "Eight new [2]rotaxanes have been prepared, incorporating an alpha-cyclodextrin as the rotor, a stilbene as the axle, and trinitrophenyl substituents as capping groups. Strategies have been devised to elaborate these by linking the rotor to the axle, to produce two new [1]rotaxanes. Rotational motion in a selection of these rotaxanes has been investigated through the application of two-dimensional NMR spectroscopy by performing TOCSY, DQF-COSY, ROESY and HMQC experiments. This has shown that a methoxyl group incorporated on the stilbene and a succinamide joining the stilbene and the cyclodextrin behave analogously to a ratchet tooth and pawl, respectively, to restrict rotation." @default.
• W2000803578 created "2016-06-24" @default.
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• W2000803578 date "2003-12-11" @default.
• W2000803578 modified "2023-10-17" @default.
• W2000803578 title "Installation of a Ratchet Tooth and Pawl To Restrict Rotation in a Cyclodextrin Rotaxane" @default.
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• W2000803578 doi "https://doi.org/10.1002/chem.200305280" @default.
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