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- W2000804232 abstract "Abstract Phenylthio substituted oligosilanes are obtained from the reaction of oligomeric silicon halides with alkali metal thiophenolates M1SPh (MI = Li, Na, K). Si—Si bonds are formed when phenylthiooli-gosilanes are reacted with alkali metal silicon compounds. Alkali metal thiophenolates, the second reaction products can be separated easily. Quite similarly, Fe—Si-bonds are obtained from phenyl-thiosilanes and Na[Fe(CO)2Cp]. In contrast to the related alkali metal halide elimination reactions of organohalooligosilanes, transmetallations are never observed in the thiophenolate reactions." @default.
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- W2000804232 date "1994-05-01" @default.
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- W2000804232 title "Darstellung und Reaktivität von Phenylthiosubstituierten Oligosilanen" @default.
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- W2000804232 doi "https://doi.org/10.1080/10426509408016383" @default.
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