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- W2000806497 abstract "We have determined the Fe3+Fe2+ ratio, S content, and the SO2−4S2− ratio (by SKα X-ray peak shift) for a suite of twelve mid-ocean ridge and backarc basin glasses. These samples range in oxidation state from two orders of magnitude below to 1.5 orders of magnitude above the Ni-NiO oxygen buffer. Sulfur speciation in the glasses is strongly dependent on magmatic oxidation state. We propose that the solubility mechanism for S in basaltic melts changes over the |O2 range which characterizes convergent margin magmas. In low |O2, sulfide saturated basaltic melts, such as most MORBs, S is present largely as S2−, and its concentration is controlled by sulfide melt-silicate melt equilibrium and varies positively with |O2. At higher |O2's, where sulfide melt becomes unstable, S concentration is controlled by melt-vapor equilibrium and decreases with increasing |O2. For the range of |O2's in the back arc basin basalts in this study (NNO−1 to NNO+1.5), S is dissolved in the silicate in both oxidized and reduced forms. For the lower |O2 end of this range, S2− dominates and equilibria involving reduced S-species control S melt concentration. At higher |O2's, the proportion of oxidized S increases and melt-vapor equilibria involving these species become more important. Because S partitions strongly into the vapor phase over the |O2 range investigated, magmatic degassing may be effective at stripping S from the melt. The low S concentrations in island arc and backarc lavas do not necessarily reflect a low S source but rather result from higher |O2 in the convergent margin environment." @default.
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- W2000806497 date "1993-08-01" @default.
- W2000806497 modified "2023-10-17" @default.
- W2000806497 title "Sulfur speciation, oxidation state, and sulfur concentration in backarc magmas" @default.
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- W2000806497 doi "https://doi.org/10.1016/0016-7037(93)90158-s" @default.
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