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• W2000808327 abstract "Cesium perfluorooctanoate molecules are investigated by NMR spectroscopy in the lamellar phase of their aqueous solution. The particular NMR method, 13C-detected, 19F-decoupled separated-local-field (SLF) spectroscopy, provides the dipolar splitting of each 13C spin to its 19F neighbors. These dipolar splittings are interpreted in terms of the molecular C−F bond order parameters of each difluoromethylene and trifluoromethyl group. The obtained variation of this order parameter along the fluoroalkyl chain strengthens the conclusion from an earlier, model-dependent study (Furó, I.; Sitnikov, R. Langmuir 1999, 15, 2669): perfluorinated surfactant chains are significantly more rigid than their hydrogenated counterparts." @default.
• W2000808327 created "2016-06-24" @default.
• W2000808327 creator A5010392700 @default.
• W2000808327 creator A5061981173 @default.
• W2000808327 date "2000-01-19" @default.
• W2000808327 modified "2023-10-16" @default.
• W2000808327 title "Order Parameter Profile of Perfluorinated Chains in a Lamellar Phase" @default.
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• W2000808327 doi "https://doi.org/10.1021/la991114v" @default.
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