Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000808809> ?p ?o ?g. }
- W2000808809 endingPage "185" @default.
- W2000808809 startingPage "178" @default.
- W2000808809 abstract "A one-pot strategy exploiting the structure directing effects of SeIV and TeIV heteroatoms has yielded the highest nuclearity noble metal containing polyoxometalates to date; including the palladium-rich selenotungstate isomers K28[H12Pd10Se10W52O206]·65H2O (1) and K26[H14Pd10Se10W52O206]·68H2O (2), and the nanoscale tellurotungstate cluster Na40[Pd6Te19W42O190]·76H2O (3). These reaction systems exhibit remarkable structural flexibility and point to a new route towards the synthesis of complex heterometallic species, in which multiple lacunary polyoxometalate ‘building blocks’ have been assembled to trap a transient oxopalladate species suspected to play a role in the assembly of several common polyoxopalladates. Mass spectrometry has been applied to explore and compare the solution stability of compounds 1–3, demonstrating the markedly different properties of the SeIV and TeIV templated systems. Electrochemical analysis of 1 has been provided and is dominated by Pd redox processes, with reduction of the cluster resulting in electrodeposition of Pd metal and observation of the subsequent formation of PdO species, concurrent with previously reported oxopalladate containing species." @default.
- W2000808809 created "2016-06-24" @default.
- W2000808809 creator A5011402814 @default.
- W2000808809 creator A5027887380 @default.
- W2000808809 creator A5060075379 @default.
- W2000808809 creator A5080208063 @default.
- W2000808809 date "2014-01-01" @default.
- W2000808809 modified "2023-10-17" @default.
- W2000808809 title "Self-assembly and structural transformations of high-nuclearity palladium-rich polyoxometalates" @default.
- W2000808809 cites W1515405481 @default.
- W2000808809 cites W1964570639 @default.
- W2000808809 cites W1970994221 @default.
- W2000808809 cites W1971430293 @default.
- W2000808809 cites W1972526033 @default.
- W2000808809 cites W1973967805 @default.
- W2000808809 cites W1975115319 @default.
- W2000808809 cites W1978383512 @default.
- W2000808809 cites W1985030796 @default.
- W2000808809 cites W1985419254 @default.
- W2000808809 cites W1986574689 @default.
- W2000808809 cites W1987117129 @default.
- W2000808809 cites W1995648328 @default.
- W2000808809 cites W1998079081 @default.
- W2000808809 cites W1999292430 @default.
- W2000808809 cites W2006048292 @default.
- W2000808809 cites W2007255696 @default.
- W2000808809 cites W2012585362 @default.
- W2000808809 cites W2014763492 @default.
- W2000808809 cites W2021931164 @default.
- W2000808809 cites W2025642255 @default.
- W2000808809 cites W2027162257 @default.
- W2000808809 cites W2032640733 @default.
- W2000808809 cites W2033580871 @default.
- W2000808809 cites W2035014388 @default.
- W2000808809 cites W2035127456 @default.
- W2000808809 cites W2035745316 @default.
- W2000808809 cites W2039216579 @default.
- W2000808809 cites W2048655173 @default.
- W2000808809 cites W2053918030 @default.
- W2000808809 cites W2060872356 @default.
- W2000808809 cites W2061006913 @default.
- W2000808809 cites W2062489235 @default.
- W2000808809 cites W2063334178 @default.
- W2000808809 cites W2066904165 @default.
- W2000808809 cites W2070024698 @default.
- W2000808809 cites W2078662446 @default.
- W2000808809 cites W2081127900 @default.
- W2000808809 cites W2090709653 @default.
- W2000808809 cites W2097002543 @default.
- W2000808809 cites W2100951188 @default.
- W2000808809 cites W2101713007 @default.
- W2000808809 cites W2101947989 @default.
- W2000808809 cites W2112903069 @default.
- W2000808809 cites W2114676756 @default.
- W2000808809 cites W2118853515 @default.
- W2000808809 cites W2126733471 @default.
- W2000808809 cites W2126839806 @default.
- W2000808809 cites W2128172145 @default.
- W2000808809 cites W2131350133 @default.
- W2000808809 cites W2137220265 @default.
- W2000808809 cites W2139077250 @default.
- W2000808809 cites W2139360094 @default.
- W2000808809 cites W2140330789 @default.
- W2000808809 cites W2140917975 @default.
- W2000808809 cites W2144332006 @default.
- W2000808809 cites W2146082431 @default.
- W2000808809 cites W2147199348 @default.
- W2000808809 cites W2150314210 @default.
- W2000808809 cites W2159576266 @default.
- W2000808809 cites W2163430070 @default.
- W2000808809 cites W2163801766 @default.
- W2000808809 cites W2172013416 @default.
- W2000808809 cites W2296036164 @default.
- W2000808809 cites W2316321596 @default.
- W2000808809 cites W2322149518 @default.
- W2000808809 cites W2328007294 @default.
- W2000808809 cites W2333328202 @default.
- W2000808809 cites W2336043143 @default.
- W2000808809 cites W2950662006 @default.
- W2000808809 cites W296827296 @default.
- W2000808809 cites W4245248076 @default.
- W2000808809 cites W4362048433 @default.
- W2000808809 doi "https://doi.org/10.1039/c3qi00075c" @default.
- W2000808809 hasPublicationYear "2014" @default.
- W2000808809 type Work @default.
- W2000808809 sameAs 2000808809 @default.
- W2000808809 citedByCount "48" @default.
- W2000808809 countsByYear W20008088092014 @default.
- W2000808809 countsByYear W20008088092015 @default.
- W2000808809 countsByYear W20008088092016 @default.
- W2000808809 countsByYear W20008088092017 @default.
- W2000808809 countsByYear W20008088092018 @default.
- W2000808809 countsByYear W20008088092019 @default.
- W2000808809 countsByYear W20008088092020 @default.
- W2000808809 countsByYear W20008088092021 @default.
- W2000808809 countsByYear W20008088092022 @default.
- W2000808809 countsByYear W20008088092023 @default.
- W2000808809 crossrefType "journal-article" @default.