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- W2000809810 abstract "Abstract The effect of dioctadecyldimethylammonium chloride (DODAC) vesicles upon the reactivity of several anthracene derivatives towards O 2 ( 1 Δ g ) has been measured. Incorporation of the substrates into the vesicles decreases their consumption rate. The effect depends on both the substrate characteristics and the vesicle size. The most pronounced decreases are observed with those substrates for which deep incorporation of the anthryl group into the vesicles could be expected, i.e. , 9,10-dimethylanthracene and 3-(9-anthryl)propionic acid. For these substrates, the reactivity is nearly two times smaller in the large (injected) vesicles than in the small (sonicated) vesicles. The dependence of the bleaching rates on the surfactant concentration allows the evaluation of the substrate distribution between the vesicles and the aqueous solution. For 9-methylanthracene and 9-anthracenemethanol, the partition constants are nearly ten times smaller in the large vesicles than in the smaller vesicles." @default.
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- W2000809810 date "1989-02-01" @default.
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- W2000809810 title "Vesicular effect on the reactivity of anthracene derivatives towards singlet molecular oxygen" @default.
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- W2000809810 doi "https://doi.org/10.1016/1011-1344(89)80025-9" @default.
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