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- W2000812085 abstract "After reduction of the second and third stage FeCl3 intercalation compounds with potassium, only graphite, α-Fe and KCl could be detected by X-ray diffraction. An analogous result was obtained by reduction of the 1st stage compound with sodium in liquid ammonia. After reduction of the 2nd/3rd stage compound with sodium dissolved in hexamethylphosphoric triamide, two additional reflections at 6.10 A and 5.21 A were observed in addition to those of graphite, α-Fe, and NaCl. The material contained appreciable quantities of phosphoric compounds which formed FePO4 on combustion. It cannot be excluded that the unidentified lines are caused by interacalation of an HMPT complex. The question of the existence of transition metal intercalation complexes in graphite metal complexes in graphite is discussed." @default.
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- W2000812085 date "1977-12-01" @default.
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- W2000812085 title "Reduction of graphite- metal chloride intercalation compounds" @default.
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- W2000812085 doi "https://doi.org/10.1016/0025-5416(77)90014-3" @default.
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