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- W2000822555 abstract "Abstract Absorption and magnetic circular dichroism studies of the F centers in NaI reveal a strong electron-lattice coupling with the vibration modes of Γ1+ symmetry in comparison with those of Γ3+ and Γ5+ symmetry. On the other hand, the F electron exhibits in its first excited state a large spin-orbit coupling, in agreement with the value previously calculated. These results are confirmed by the Raman spectra which show a predominant intensity for the Γ1+ modes, particularly for the resonant mode at 113 cm−1. First and second-order Raman spectra have been calculated using a “quasi-resonant” theory in which the vibrations of the ions up to the fifth shell have been taken into consideration. We have been able to determine from these calculations absolute values for the contributions of the different types of vibration modes to the broadening of the F-absorption band." @default.
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- W2000822555 date "1980-03-01" @default.
- W2000822555 modified "2023-09-25" @default.
- W2000822555 title "Electron-lattice coupling of F centers: Particular case of NaI: F" @default.
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- W2000822555 doi "https://doi.org/10.1016/0038-1098(80)91086-8" @default.
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