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- W2000823067 abstract "Four unique 2-arylethenyl-8-hydroxyquinoline ligands (B1–B4) and their corresponding Zn(II) complexes (C1–C4) were synthesized and characterized by 1H NMR, ESI-MS, FTIR, and elemental analysis. The aggregation behavior of Zinc salt and ligands in solution was investigated by several techniques, including 1H NMR, UV–vis, and photoluminescence (PL). The electronic nature of arylethenyl substituents affects the absorption wavelength, the emission color, fluorescence lifetime, fluorescence quantum yield, and thermostability of Zn(II) complexes. Luminescent properties of the Zn(II) complexes correspond to the electron-withdrawing/-donating character of the arylethenyl substituents. Photophysical analyses combined with density functional theory (DFT) calculations established that the introduction of strong electron-withdrawing group (CN) decreased the HOMO–LUMO energy gap, and the introduction of electron-donating group (tert-butyl) enlarged the HOMO–LUMO energy gap." @default.
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- W2000823067 date "2013-11-01" @default.
- W2000823067 modified "2023-10-17" @default.
- W2000823067 title "Impact of substituents on the luminescent properties and thermostability of Zn(II) 8-hydroxyquinolinates: insight from experimental and theoretical approach" @default.
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- W2000823067 doi "https://doi.org/10.1016/j.tet.2013.09.064" @default.
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