FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000823886> ?p ?o ?g. }

• W2000823886 endingPage "782" @default.
• W2000823886 startingPage "769" @default.
• W2000823886 abstract "To date, a wide range of industrial materials such as solvents, fuels, synthetic fibers, and chemical products are being manufactured from petroleum resources. However, rapid depletion of fossil and petroleum resources is encouraging current and future chemists to orient their research toward designing safer chemicals, products, and processes from renewable feedstock with an increased awareness of environmental and industrial impact. Advances in genetics, biotechnology, process chemistry, and engineering are leading to a new manufacturing concept for converting renewable biomass to valuable fuels and products, generally known as the biorefinery concept. The swift integration of crop-based materials synthesis and biorefinery manufacturing technologies offers the potential for new advances in sustainable energy alternatives and biomaterials that will lead to a new manufacturing paradigm. This Account presents a novel and emerging concept of generating various forms of soft materials from crops (an alternate feedstock). In future research, developing biobased soft materials will be a fascinating yet demanding practice, which will have direct impact on industrial applications as an economically viable alternative. Here we discuss some remarkable examples of glycolipids generated from industrial byproducts such as cashew nut shell liquid, which upon self-assembly produced soft nanoarchitectures including lipid nanotubes, twisted/helical nanofibers, low-molecular-weight gels, and liquid crystals. Synthetic methods applied to a chiral pool of carbohydrates using the selectivity of enzyme catalysis yield amphiphilic products derived from biobased feedstock including amygdalin, trehalose, and vitamin C. This has been achieved with a lipase-mediated regioselective synthetic procedure to obtain such amphiphiles in quantitative yields. Amygdalin amphiphiles showed unique gelation behavior in a broad range of solvents such as nonpolar hexanes to polar aqueous solutions. Importantly, an enzyme triggered drug-delivery model for hydrophobic drugs was demonstrated by using these supramolecularly assembled hydrogels. Following a similar biocatalytic approach, vitamin C amphiphiles were synthesized with different hydrocarbon chain lengths, and their ability to self-assemble into molecular gels and liquid crystals has been studied in detail. Such biobased soft materials were successfully used to develop novel organic-inorganic hybrid materials by in situ synthesis of metal nanoparticles. The self-assembled soft materials were characterized by several spectroscopic techniques, UV-visible, infrared, and fluorescence spectrophotometers, as well as microscopic methods including polarized optical, confocal, scanning, and transmission electron microscopes, and thermal analysis. The molecular packing of the hierarchically assembled bilayer membranes was fully elucidated by X-ray analysis. We envision that the results summarized in this Account will encourage interdisciplinary collaboration between scientists in the fields of organic synthesis, soft materials research, and green chemistry to develop functional materials from underutilized crop-based renewable feedstock, with innovation driven both by material needs and environmentally benign design principles." @default.
• W2000823886 created "2016-06-24" @default.
• W2000823886 creator A5042223305 @default.
• W2000823886 creator A5066638992 @default.
• W2000823886 date "2008-05-29" @default.
• W2000823886 modified "2023-09-25" @default.
• W2000823886 title "Crops: A Green Approach toward Self-Assembled Soft Materials" @default.
• W2000823886 cites W1602147337 @default.
• W2000823886 cites W1678327261 @default.
• W2000823886 cites W1973482098 @default.
• W2000823886 cites W1973623904 @default.
• W2000823886 cites W1983183895 @default.
• W2000823886 cites W1984704633 @default.
• W2000823886 cites W1991660232 @default.
• W2000823886 cites W1995773608 @default.
• W2000823886 cites W1997084024 @default.
• W2000823886 cites W1998321859 @default.
• W2000823886 cites W2004213438 @default.
• W2000823886 cites W2006076266 @default.
• W2000823886 cites W2015492344 @default.
• W2000823886 cites W2021962745 @default.
• W2000823886 cites W2024432714 @default.
• W2000823886 cites W2025815449 @default.
• W2000823886 cites W2028420909 @default.
• W2000823886 cites W2041136418 @default.
• W2000823886 cites W2041246471 @default.
• W2000823886 cites W2045269559 @default.
• W2000823886 cites W2052361724 @default.
• W2000823886 cites W2053658458 @default.
• W2000823886 cites W2053885191 @default.
• W2000823886 cites W2054432898 @default.
• W2000823886 cites W2054920634 @default.
• W2000823886 cites W2056802850 @default.
• W2000823886 cites W2057463855 @default.
• W2000823886 cites W2062486776 @default.
• W2000823886 cites W2068309299 @default.
• W2000823886 cites W2068625259 @default.
• W2000823886 cites W2069172278 @default.
• W2000823886 cites W2075606612 @default.
• W2000823886 cites W2081628968 @default.
• W2000823886 cites W2088169918 @default.
• W2000823886 cites W2103099844 @default.
• W2000823886 cites W2105503244 @default.
• W2000823886 cites W2105552426 @default.
• W2000823886 cites W2108723745 @default.
• W2000823886 cites W2123647269 @default.
• W2000823886 cites W2126819812 @default.
• W2000823886 cites W2127332314 @default.
• W2000823886 cites W2127853055 @default.
• W2000823886 cites W2130543873 @default.
• W2000823886 cites W2141860146 @default.
• W2000823886 cites W2143266713 @default.
• W2000823886 cites W2146962477 @default.
• W2000823886 cites W2156350829 @default.
• W2000823886 cites W2186274569 @default.
• W2000823886 cites W2316150456 @default.
• W2000823886 cites W4233550518 @default.
• W2000823886 cites W4323285386 @default.
• W2000823886 doi "https://doi.org/10.1021/ar7002682" @default.
• W2000823886 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18507403" @default.
• W2000823886 hasPublicationYear "2008" @default.
• W2000823886 type Work @default.
• W2000823886 sameAs 2000823886 @default.
• W2000823886 citedByCount "168" @default.
• W2000823886 countsByYear W20008238862012 @default.
• W2000823886 countsByYear W20008238862013 @default.
• W2000823886 countsByYear W20008238862014 @default.
• W2000823886 countsByYear W20008238862015 @default.
• W2000823886 countsByYear W20008238862016 @default.
• W2000823886 countsByYear W20008238862017 @default.
• W2000823886 countsByYear W20008238862018 @default.
• W2000823886 countsByYear W20008238862019 @default.
• W2000823886 countsByYear W20008238862020 @default.
• W2000823886 countsByYear W20008238862021 @default.
• W2000823886 countsByYear W20008238862022 @default.
• W2000823886 countsByYear W20008238862023 @default.
• W2000823886 crossrefType "journal-article" @default.
• W2000823886 hasAuthorship W2000823886A5042223305 @default.
• W2000823886 hasAuthorship W2000823886A5066638992 @default.
• W2000823886 hasConcept C119599485 @default.
• W2000823886 hasConcept C127413603 @default.
• W2000823886 hasConcept C150903083 @default.
• W2000823886 hasConcept C154881586 @default.
• W2000823886 hasConcept C15920480 @default.
• W2000823886 hasConcept C161790260 @default.
• W2000823886 hasConcept C171250308 @default.
• W2000823886 hasConcept C178790620 @default.
• W2000823886 hasConcept C183696295 @default.
• W2000823886 hasConcept C185592680 @default.
• W2000823886 hasConcept C188573790 @default.
• W2000823886 hasConcept C192562407 @default.
• W2000823886 hasConcept C206139338 @default.
• W2000823886 hasConcept C2780301381 @default.
• W2000823886 hasConcept C521977710 @default.
• W2000823886 hasConcept C67407626 @default.
• W2000823886 hasConcept C86803240 @default.
• W2000823886 hasConcept C91558341 @default.
• W2000823886 hasConceptScore W2000823886C119599485 @default.

• next