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- W2000826020 abstract "Abstract Acid waters containing aluminum ions have been contacted with limestone in a stirred tank reactor, in order to neutralize the solution and promote aluminum separation as hydroxide. The limestone dissolution rate has been measured over a wide range of experimental conditions. The influence of solid surface area, stirring rate, temperature, liquid composition and flowrate of the inert stripping gas have been studied. The results suggest that the limestone dissolution rate is limited by diffusion at the solid—liquid interface, and that the precipitation of aluminum hydroxide and the CO 2 desorption are also rate-determining steps. The presence of H 2 CO 3 in the liquid, owing to the slowness of CO 2 desorption, plays a beneficial role in the overall rate of limestone dissolution. A model has been developed, based on the diffusion of ionic and molecular species towards and from the solid surface, which is able to predict the experimental data within the explored range of the variables. The conclusion is drawn that limestone might be a promising alternative to other neutralizing agents for acid waters." @default.
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- W2000826020 date "1981-01-01" @default.
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- W2000826020 title "Neutralization of acid waters containing aluminum ions by means of limestone" @default.
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- W2000826020 doi "https://doi.org/10.1016/0300-9467(81)80054-8" @default.
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