FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000826647> ?p ?o ?g. }

• W2000826647 endingPage "1604" @default.
• W2000826647 startingPage "1596" @default.
• W2000826647 abstract "A new family of strontium and barium guanidinate complexes were synthesized from SrI2, [Sr{N(SiMe3)2}2]2, [Ba{N(SiMe3)2}2(THF)1.6], Sr(Cp*)2, and Ba(Cp*)2(THF)1.7 metal reactants and appropriate guanidine or guanidinate ligand (Cp* = pentamethylcyclopentadienide). Treatment of [Sr{N(SiMe3)2}2]2 with 4.0 equiv of iPrN═C(NMe2)N(H)iPr (1LH) or iPrN═C(N(iPr)2)N(H)iPr (2LH) gave dimeric complexes [(η2-1L)Sr(μ2,η2:η2-1L)(μ2,η1:η1-1L)Sr(η2-1L)] (3) and [(η2-2L)Sr(μ2,η2:η2-2L)2Sr(η2-2L)] (4), respectively. Related reactions of 1LH and 2LH with 1.0 equiv of Sr(Cp*)2 afforded the mixed-ligand complexes [(Cp*)Sr(μ2,η2:η2-1L)2Sr(Cp*)] (5) and [(Cp*)Sr(μ2,η2:η2-2L)2Sr(Cp*)] (6), respectively, with simultaneous liberation of Cp*H. Treatment of [Ba{N(SiMe3)2}2(THF)1.6] with 2.0 equiv of 2LH gave the dimer [(η2-2L)Ba(μ2,η2:η2-2L)2Ba(η2-2L)] (7), while reaction of Ba(Cp*)2(THF)1.7 with 2LH afforded guanidinate-bridged [(Cp*)Ba(μ2,η2:η2-2L)2Ba(Cp*)] (8). Reaction of SrI2 with 2.0 equiv of Na[(iPr)NC(N(SiMe3)2)N(iPr)] (9LNa) in diethyl ether gave monomeric [Sr(η2-9L)2OEt2] (10). The solid-state structures of 3, 4, 6, 7, 8, and 10 are reported. Reactions of 4 and 6 with certain Lewis bases are also described." @default.
• W2000826647 created "2016-06-24" @default.
• W2000826647 creator A5035863225 @default.
• W2000826647 creator A5055170617 @default.
• W2000826647 creator A5056844262 @default.
• W2000826647 creator A5057803757 @default.
• W2000826647 date "2008-03-08" @default.
• W2000826647 modified "2023-10-03" @default.
• W2000826647 title "Synthesis and Structure of Strontium and Barium Guanidinates and Mixed-Ligand Guanidinate Pentamethylcyclopentadienyl Complexes" @default.
• W2000826647 cites W1967077702 @default.
• W2000826647 cites W1967917399 @default.
• W2000826647 cites W1974625750 @default.
• W2000826647 cites W1978834139 @default.
• W2000826647 cites W1981607372 @default.
• W2000826647 cites W1988431858 @default.
• W2000826647 cites W1996939135 @default.
• W2000826647 cites W1998581261 @default.
• W2000826647 cites W2005014777 @default.
• W2000826647 cites W2012157062 @default.
• W2000826647 cites W2015989455 @default.
• W2000826647 cites W2016450145 @default.
• W2000826647 cites W2018032182 @default.
• W2000826647 cites W2019680506 @default.
• W2000826647 cites W2035820652 @default.
• W2000826647 cites W2036183766 @default.
• W2000826647 cites W2042686068 @default.
• W2000826647 cites W2045966238 @default.
• W2000826647 cites W2048510918 @default.
• W2000826647 cites W2052615892 @default.
• W2000826647 cites W2067052186 @default.
• W2000826647 cites W2068475092 @default.
• W2000826647 cites W2072307168 @default.
• W2000826647 cites W2080136247 @default.
• W2000826647 cites W2082694606 @default.
• W2000826647 cites W2082927362 @default.
• W2000826647 cites W2086553486 @default.
• W2000826647 cites W2090292190 @default.
• W2000826647 cites W2094445302 @default.
• W2000826647 cites W2105249240 @default.
• W2000826647 cites W2109687731 @default.
• W2000826647 cites W2139967227 @default.
• W2000826647 cites W2155324802 @default.
• W2000826647 cites W2164456181 @default.
• W2000826647 cites W2165408455 @default.
• W2000826647 cites W2323189565 @default.
• W2000826647 cites W2338768700 @default.
• W2000826647 cites W2950411220 @default.
• W2000826647 cites W2951255873 @default.
• W2000826647 cites W2951597009 @default.
• W2000826647 doi "https://doi.org/10.1021/om701118j" @default.
• W2000826647 hasPublicationYear "2008" @default.
• W2000826647 type Work @default.
• W2000826647 sameAs 2000826647 @default.
• W2000826647 citedByCount "28" @default.
• W2000826647 countsByYear W20008266472012 @default.
• W2000826647 countsByYear W20008266472013 @default.
• W2000826647 countsByYear W20008266472014 @default.
• W2000826647 countsByYear W20008266472015 @default.
• W2000826647 countsByYear W20008266472016 @default.
• W2000826647 countsByYear W20008266472018 @default.
• W2000826647 countsByYear W20008266472019 @default.
• W2000826647 countsByYear W20008266472020 @default.
• W2000826647 countsByYear W20008266472021 @default.
• W2000826647 countsByYear W20008266472022 @default.
• W2000826647 countsByYear W20008266472023 @default.
• W2000826647 crossrefType "journal-article" @default.
• W2000826647 hasAuthorship W2000826647A5035863225 @default.
• W2000826647 hasAuthorship W2000826647A5055170617 @default.
• W2000826647 hasAuthorship W2000826647A5056844262 @default.
• W2000826647 hasAuthorship W2000826647A5057803757 @default.
• W2000826647 hasConcept C107814960 @default.
• W2000826647 hasConcept C116569031 @default.
• W2000826647 hasConcept C147789679 @default.
• W2000826647 hasConcept C155647269 @default.
• W2000826647 hasConcept C170493617 @default.
• W2000826647 hasConcept C178790620 @default.
• W2000826647 hasConcept C179104552 @default.
• W2000826647 hasConcept C185592680 @default.
• W2000826647 hasConcept C2776721371 @default.
• W2000826647 hasConcept C2779546866 @default.
• W2000826647 hasConcept C518915863 @default.
• W2000826647 hasConcept C542576722 @default.
• W2000826647 hasConcept C55493867 @default.
• W2000826647 hasConcept C71240020 @default.
• W2000826647 hasConcept C8010536 @default.
• W2000826647 hasConceptScore W2000826647C107814960 @default.
• W2000826647 hasConceptScore W2000826647C116569031 @default.
• W2000826647 hasConceptScore W2000826647C147789679 @default.
• W2000826647 hasConceptScore W2000826647C155647269 @default.
• W2000826647 hasConceptScore W2000826647C170493617 @default.
• W2000826647 hasConceptScore W2000826647C178790620 @default.
• W2000826647 hasConceptScore W2000826647C179104552 @default.
• W2000826647 hasConceptScore W2000826647C185592680 @default.
• W2000826647 hasConceptScore W2000826647C2776721371 @default.
• W2000826647 hasConceptScore W2000826647C2779546866 @default.
• W2000826647 hasConceptScore W2000826647C518915863 @default.
• W2000826647 hasConceptScore W2000826647C542576722 @default.
• W2000826647 hasConceptScore W2000826647C55493867 @default.

• next