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- W2000828916 abstract "The title polymeric compound, catena-poly[dipotassium [bis[mu-N-salicylidene-beta-alaninato(2-)]-kappa(4)O,N,O':O;kappa(4)O:O,N,O'-dicopper(II)]-di-mu-isothiocyanato-kappa(2)N:S;kappa(2)S:N], [K[Cu(NCS)(C(10)H(9)NO(3))]](n), consists of [isothiocyanato(N-salicylidene-beta-alaninato)copper(II)](-) anions connected through the two three-atom thiocyanate (mu-NCS) and the two anti,anti-mu-carboxylate bridges into infinite one-dimensional polymeric anions, with coulombically interacting K(+) counter-ions with coordination number 7 constrained between the chains. The Cu(II) atoms adopt a distorted tetragonal-bipyramidal coordination, with three donor atoms of the tridentate Schiff base and one N atom of the bridging mu-NCS ligand in the basal plane. The first axial position is occupied by a thiocyanate S atom of a symmetry-related mu-NCS ligand at an apical distance of 2.9770 (8) A, and the second position is occupied by an O atom of a bridging carboxylate group from an adjacent coordination unit at a distance of 2.639 (2) A." @default.
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- W2000828916 date "2003-11-08" @default.
- W2000828916 modified "2023-10-18" @default.
- W2000828916 title "<i>catena</i>-Poly[potassium [copper(II)-μ-isothiocyanato-μ-<i>N</i>-salicylidene-β-alaninato(2–)]]" @default.
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- W2000828916 doi "https://doi.org/10.1107/s0108270103023151" @default.
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