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- W2000832344 abstract "The chelate phosphanes Diphos, Diop, and Norphos were reacted with C 5 H 5 Mn(CO) 2 THF and CH 3 C 5 H 4 Mn(CO) 2 THF to give mononuclear complexes, containing the phosphanes as unidentate or as bidentate ligands, and dinuclear complexes, containing bridging phosphane ligands. In C 5 H 5 Mn(CO) 2 Diop one of the two P(C 6 H 5 ) 2 groups of Diop is coordinated to the C 5 H 5 Mn(CO) 2 fragment; the uncoordinated P(C 6 H 5 ) 2 group makes it a monodentate ligand. C 5 H 5 Mn(CO) 2 Diop together with [Rh(cod)Cl] 2 was used as an in situ catalyst in the enantioselective hydrogenation of (Z)-a-[N -acetam ino]cinnamic acid (78.4% ee) and in the enantioselective hydrosilylation of acetophenone with diphenylsilane (6.7% ee)." @default.
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- W2000832344 date "1985-10-01" @default.
- W2000832344 modified "2023-09-23" @default.
- W2000832344 title "Asymmetrische Katalysen, 25 [1]. C5H5Mn(CO)2-Komplexe von optisch aktiven Chelatphosphanen als einzähnige Liganden in der enantioselektiven Katalyse / Asymmetric Catalyses, 25 [1]. C5H5Mn(CO)2 Complexes of Optically Active Chelate Phosphanes as Monodentate Ligands in Enantioselective Catalysis" @default.
- W2000832344 doi "https://doi.org/10.1515/znb-1985-1004" @default.
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