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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000833054> ?p ?o ?g. }

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• W2000833054 abstract "The synthesis of highly functionalized pyrimidinyl arylglycines is presented. The highlight in our synthetic sequence includes selective O-alkylation of 2-(benzylsulfanyl)-4(3H)-pyrimidinones with N-Boc β-aminoalcohols under Mitsunobu conditions, Petasis reaction with glyoxylic acid and phenylboronic acid and nucleophilic ipso-substitution of the activated sulfur with morpholine. The unexpected spontaneous Smiles rearrangement of several pyrimidinyl amines is also discussed." @default.
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• W2000833054 date "2008-05-01" @default.
• W2000833054 modified "2023-09-25" @default.
• W2000833054 title "Synthesis of pyrimidinyl arylglycines through subsequent Mitsunobu and Petasis reactions" @default.
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• W2000833054 doi "https://doi.org/10.1016/j.tet.2008.03.035" @default.
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