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- W2000834465 abstract "Abstract Electrophoretic studies with particular reference to isoelectric point values have been made with rutile prepared by hydrolysis of titanium tetrachloride. Comparison of the rutile with that treated with hydrogen chloride shows the chloride impurity remaining after hydrolysis to be ionic in nature and distributed both on the surface and in the bulk of the material. Hydrogen chloride gas reacts predominantly with surface TiOH and TiOTi sites producing TiCl species which differ from those associated with the impurity. Silanol groups are formed on rutile by treatment with silicon tetrachloride followed by water vapor giving a surface which, from electrophoretic data, is shown to be dissimilar to the mixed oxide silica-titania, but similar to rutile onto which hydrated silica is precipitated." @default.
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- W2000834465 date "1972-12-01" @default.
- W2000834465 modified "2023-09-27" @default.
- W2000834465 title "An electrophoretic investigation of the effect of chloride and of silanol groups on the properties of the surface of rutile" @default.
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