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• W2000834530 endingPage "5388" @default.
• W2000834530 startingPage "5386" @default.
• W2000834530 abstract "Treatment of M(NAr)2(Cl)2(DME), where Ar = 2,6-diisopropylphenyl, with cyclooctyne results in the formation of M(C8H12C8H12NAr)(Cl)2(NAr), where M = Mo (1) and W (2). The complexes have metrical and spectroscopic parameters that are most consistent with an alkylidene-imine formulation with some participation by the alkyl-amido resonance form. Thermolysis of metallacycles 1 and 2 generates a pyrrole elimination product, with the tungsten derivative being more thermally stable. In addition, the metallacycle is quite hydrolytically stable. Addition of 50% H2SO4 to a toluene solution of 2 protolytically cleaves all the ligands on the metal except those associated with the metallacycle, which are retained in the oxo product [W(O)(μ-O)(C8H12C8H12NAr)]2 (3). The metallacycles 1−3 will polymerize norbornene in the presence of AlCl3. Compounds 1−3 and the pyrrole were characterized by X-ray diffraction." @default.
• W2000834530 created "2016-06-24" @default.
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• W2000834530 date "2004-10-07" @default.
• W2000834530 modified "2023-09-26" @default.
• W2000834530 title "Group-6 Imido Activation by a Ring-Strained Alkyne" @default.
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• W2000834530 doi "https://doi.org/10.1021/om049262q" @default.
• W2000834530 hasPublicationYear "2004" @default.
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