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• W2000839632 abstract "Matrix-isolated 2-benzothienyl(trifluoromethyl)carbene was generated by irradiation of the corresponding diazirine, and characterized by IR and UV/vis spectroscopy, in situ trapping, and DFT modeling. Experiments and calculations indicate that the carbene is a ground-state singlet, in contrast to previously characterized aryl(trifluoromethyl)carbenes. The carbene could be interconverted photochemically with a ring-opened thioquinomethide and a highly strained cyclic allene." @default.
• W2000839632 created "2016-06-24" @default.
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• W2000839632 creator A5032764121 @default.
• W2000839632 date "2007-07-14" @default.
• W2000839632 modified "2023-09-24" @default.
• W2000839632 title "A Singlet Aryl-CF₃ Carbene: 2-Benzothienyl(trifluoromethyl)carbene and Interconversion with a Strained Cyclic Allene" @default.
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• W2000839632 doi "https://doi.org/10.1021/ol071290s" @default.
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