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• W2000840224 abstract "Abstract Doubly charged systems derived from fused benzenoid polycycles reveal an unquenched delocalization of 4 n π-electrons and hence are predicted to possess antiaromatic character. The magnitude of the paratropic 1 H NMR chemical shifts, due solely to the paramagnetic secondary field sustained in these species, was found to depend linearly upon the magnitude of LUMO-HOMO energy gaps of the corresponding systems. The existence of such a correlation enables a comprehensive treatment of the various factors which determine the antiaromatic character and the subtle interrelations between those factors. This, in turn, leads to a deeper understanding of antiaromaticity." @default.
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• W2000840224 date "1985-01-01" @default.
• W2000840224 modified "2023-09-24" @default.
• W2000840224 title "Paratropicity and antiaromaticity: role of the homo-lumo energy gap" @default.
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• W2000840224 doi "https://doi.org/10.1016/s0040-4020(01)96458-0" @default.
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