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- W2000840913 abstract "The photochemical ring expansion of N-vinyl-2-pyrrolidone (NVP) has been carried out at 254 nm. The reaction quantum yield depends a great deal on the solvnet viscosity and temperature. The recombination time of the biradical of RP produced by Norrish type I fission was estimated to be ≈10−10 s by application of the Einstein and Smoluchowski-Debye equations. The spin inversion of the biradical in a solvent cage is also discussed according to Kaptein’s theory of the radical-pair mechanism." @default.
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- W2000840913 date "1977-08-01" @default.
- W2000840913 modified "2023-10-14" @default.
- W2000840913 title "Mechanism of the Photochemical Ring Expansion of<i>N</i>-Vinyl-2-pyrrolidone. Estimation of the Recombination-Time of Biradical" @default.
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- W2000840913 doi "https://doi.org/10.1246/bcsj.50.2067" @default.
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