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- W2000843994 abstract "Proton transfer equilibria [Formula: see text] and NO + transfer equilibria [Formula: see text] have been studied for the following bases B, benzene, toluene, o-, m-, and p-xylene. NO + transfer equilibria for fluoro- and chlorobenzene have also been studied. Pulsed electron beam, high-pressure ion source mass spectrometry has been used to obtain the equilibrium constant K and hence the free energy changes ΔG 0 and from van't Hoff plots, ΔH 0 and ΔS 0 . Entropy changes are in general much smaller for NO + transfer than for H + transfer but the magnitude of the changes in the proton affinity and NO + affinity of toluene caused by a fluorine substituent is about the same, even though the absolute value of the proton affinity is greater by a factor of 4. The position of the F substituent on toluene has a marked effect on proton affinity but no effect on NO + affinity. The latter appears to be responsive only to the inductive effect." @default.
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- W2000843994 date "1982-04-01" @default.
- W2000843994 modified "2023-09-25" @default.
- W2000843994 title "A comparison of the relative binding energies of H+ and NO+ to aromatic and haloaromatic bases by high pressure mass spectrometry" @default.
- W2000843994 doi "https://doi.org/10.1139/v82-136" @default.
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