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• W2000844227 endingPage "12879" @default.
• W2000844227 startingPage "12873" @default.
• W2000844227 abstract "The mechanism of [{RuCl2(p-cymene)}2]-catalyzed oxidative annulations of isoquinolones with alkynes was investigated in detail. The first step is an acetate-assisted CH bond activation process to form cyclometalated compounds. Subsequent mono-alkyne insertion of the RuC bonds of the cyclometalated compounds then takes place. Finally, oxidative coupling of the CN bond of the insertion compounds occurs to afford Ru0 sandwich complexes that undergo oxidation to regenerate the catalytically active RuII complex with the copper oxidant and release the desired dibenzo[a,g]quinolizin-8-one derivatives. All of the relevant intermediates were fully characterized and determined by single crystal X-ray diffraction analysis. The [{RuCl2(p-cymene)}2]-catalyzed CH bond functionalization of isoquinolones with alkynes to synthesize dibenzo[a,g]quinolizin-8-one derivatives through CH/NH activation was also demonstrated." @default.
• W2000844227 created "2016-06-24" @default.
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• W2000844227 creator A5089813280 @default.
• W2000844227 date "2012-08-28" @default.
• W2000844227 modified "2023-10-16" @default.
• W2000844227 title "Ruthenium-Catalyzed Oxidative Coupling/Cyclization of Isoquinolones with Alkynes through CH/NH Activation: Mechanism Study and Synthesis of Dibenzo[<i>a</i>,<i>g</i>]quinolizin-8-one Derivatives" @default.
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• W2000844227 doi "https://doi.org/10.1002/chem.201201862" @default.
• W2000844227 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22930580" @default.
• W2000844227 hasPublicationYear "2012" @default.
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