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• W2000861702 abstract "The diaqua complexes of trans-[Pd(py)2Cl2] (Py-pyridine), cis-[Pd(edta)Cl2] (edta-ethylene diamine tetraacetic acid) (complex A), cis-[Pd(temed)Cl2] (temed-N,N,N′,N′-tetramethylethylene diamine) and cis-1,2-bis-(2-formylglycinebenzenesulfenyl)ethane (Pd(II) dichloride (complex C) react with methionine-containing dipeptides (AcMet-aa) (aa-amino acid) via the thioether group in the methionyl side chain. The trans-Pd(py)2(H2O)2]2+ and cis-[Pd(temed)(H2O)2]2+ yield binuclear complex [Pd2(μ-AcMet-aa)2(H2O)4]4+, the diaqua complexes of complex A and complex C yield mononuclear complexes, [PdL(AcMet-aa)(H2O)]2+ (L-edta, 1,2-bis(2-formylglycinebenzenesulfenyl)ethane). These reactions and hydrolytic cleavage of the Met-aa amide bond in the coordinated AcMet-aa are conveniently monitored by 1H NMR spectroscop. The trans-Pd(py)2(H2O)2]2+ is a very efficient promoter. The hydrolytic rate promoted by it is almost equal to that promoted by [Pd(H2O)3(OH)]+, the fastest one up to now. Although reaction of rans-[Pd(py)2(H2O)2]2+ and cis-[Pd(temed)(H2O)2]2+ with AcMet-aa yield the same binuclear complex, [Pd2(μ-AcMet-aa)2(H2O)4]4+, the kinetic data showed that the hydrolytic rate promoted by cis-[Pd(temed)(H2O)2]2+ was actually controlled by temed release. The new mononuclear complexes, [PdL(AcMet-aa)H2O]2+, observed for the first time, are also hydrolytically active. It is of interest because they are closely associated with protein cleavage promoted by simple mononuclear Pd(II) complexes." @default.
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• W2000861702 date "1998-01-01" @default.
• W2000861702 modified "2023-09-30" @default.
• W2000861702 title "Hydrolysis of methionine-containing peptides in binuclear and mononuclear palladium(II) complexes" @default.
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• W2000861702 doi "https://doi.org/10.1016/s0277-5387(98)00010-2" @default.
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