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- W2000862731 abstract "Synthesis and characterizations are reported for three diruthenium(II,III) compounds of general formula Ru2(ap)4(CCR), where ap=2-anilinopyridinate and R=Si(CH3)3 (3), H (4), and CH2OCH3 (5). Molecular structure determination reveals that the Ru–Ru bond lengths are 2.3162(5) and 2.3234(7) Å for 3 and 5, respectively, while the CC bond is not significantly elongated compared with the free alkyne. Compounds 3–5 undergo reversible one-electron oxidation and reduction at potentials around 200 and −1030 mV, respectively. At more positive potential, compounds 3 and 4 undergo the second one-electron oxidation quasireversibly or irreversibly without decomposition, while compound 5 is oxidatively degraded." @default.
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- W2000862731 date "2000-02-01" @default.
- W2000862731 modified "2023-09-24" @default.
- W2000862731 title "Ru-σ-alkynyl compounds of tetraanilinopyridinato-diruthenium(II,III) core: synthesis and structural characterization" @default.
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- W2000862731 doi "https://doi.org/10.1016/s0022-328x(99)00642-7" @default.
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