Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000865549> ?p ?o ?g. }
- W2000865549 endingPage "330" @default.
- W2000865549 startingPage "309" @default.
- W2000865549 abstract "Ruthenium complexes with the non-innocent ligands (NILs) benzoquinone, iminobenzoquinone and benzoquinonediimine and their redox derivatives exhibit intriguing electronic properties. With the proper ligand set the NIL π* orbitals mix extensively with the ruthenium dπ orbitals resulting in delocalized electron distributions and non-integer oxidation states, and in most of these systems a particular ruthenium oxidation state dominates. This review critically examines the electronic structure of Ru–NIL systems from both an experimental and computational (DFT) perspective. The electron distribution within these complexes can be modulated by altering both the ancillary ligands and the NIL, and in a few cases the resultant electron distributions are exploited for catalysis. The Ru–NIL systems that perform alcohol oxidation and water oxidation catalysis are discussed in detail. The Tanaka catalyst, an anthracene-bridged dinuclear Ru complex, is an intriguing example of a Ru–NIL framework in catalysis. Unlike other known ruthenium water oxidation catalysts, the two Ru atoms remain low valent during the catalytic cycle according to DFT calculations, some experimental evidence, and predictions based on the behavior of the related mononuclear species." @default.
- W2000865549 created "2016-06-24" @default.
- W2000865549 creator A5017611605 @default.
- W2000865549 creator A5023705060 @default.
- W2000865549 creator A5038176504 @default.
- W2000865549 creator A5041812846 @default.
- W2000865549 creator A5075740866 @default.
- W2000865549 date "2010-02-01" @default.
- W2000865549 modified "2023-10-16" @default.
- W2000865549 title "Ruthenium complexes with non-innocent ligands: Electron distribution and implications for catalysis" @default.
- W2000865549 cites W162224610 @default.
- W2000865549 cites W1707354739 @default.
- W2000865549 cites W1945392034 @default.
- W2000865549 cites W1963895753 @default.
- W2000865549 cites W1963935794 @default.
- W2000865549 cites W1964170932 @default.
- W2000865549 cites W1964380846 @default.
- W2000865549 cites W1964433563 @default.
- W2000865549 cites W1965979658 @default.
- W2000865549 cites W1967422230 @default.
- W2000865549 cites W1967695001 @default.
- W2000865549 cites W1968622011 @default.
- W2000865549 cites W1970251497 @default.
- W2000865549 cites W1970393749 @default.
- W2000865549 cites W1972312364 @default.
- W2000865549 cites W1972463141 @default.
- W2000865549 cites W1972593699 @default.
- W2000865549 cites W1973346121 @default.
- W2000865549 cites W1973518002 @default.
- W2000865549 cites W1973721002 @default.
- W2000865549 cites W1976314435 @default.
- W2000865549 cites W1976370285 @default.
- W2000865549 cites W1981768663 @default.
- W2000865549 cites W1986829915 @default.
- W2000865549 cites W1988234773 @default.
- W2000865549 cites W1989917955 @default.
- W2000865549 cites W1990259685 @default.
- W2000865549 cites W1991652943 @default.
- W2000865549 cites W1994561502 @default.
- W2000865549 cites W1995778192 @default.
- W2000865549 cites W1996488673 @default.
- W2000865549 cites W1998702939 @default.
- W2000865549 cites W2000578098 @default.
- W2000865549 cites W2001306059 @default.
- W2000865549 cites W2001465174 @default.
- W2000865549 cites W2002576040 @default.
- W2000865549 cites W2002669260 @default.
- W2000865549 cites W2004457083 @default.
- W2000865549 cites W2005057455 @default.
- W2000865549 cites W2005490110 @default.
- W2000865549 cites W2006586366 @default.
- W2000865549 cites W2007200392 @default.
- W2000865549 cites W2010701680 @default.
- W2000865549 cites W2011137864 @default.
- W2000865549 cites W2012046411 @default.
- W2000865549 cites W2012888156 @default.
- W2000865549 cites W2015089498 @default.
- W2000865549 cites W2015935433 @default.
- W2000865549 cites W2019285747 @default.
- W2000865549 cites W2019322569 @default.
- W2000865549 cites W2021616354 @default.
- W2000865549 cites W2022022056 @default.
- W2000865549 cites W2022884415 @default.
- W2000865549 cites W2023525861 @default.
- W2000865549 cites W2026156302 @default.
- W2000865549 cites W2026673235 @default.
- W2000865549 cites W2027054748 @default.
- W2000865549 cites W2028380056 @default.
- W2000865549 cites W2031406148 @default.
- W2000865549 cites W2032302694 @default.
- W2000865549 cites W2032812101 @default.
- W2000865549 cites W2032839609 @default.
- W2000865549 cites W2033033156 @default.
- W2000865549 cites W2035169292 @default.
- W2000865549 cites W2036595301 @default.
- W2000865549 cites W2037262965 @default.
- W2000865549 cites W2037832728 @default.
- W2000865549 cites W2039294840 @default.
- W2000865549 cites W2039459422 @default.
- W2000865549 cites W2039748176 @default.
- W2000865549 cites W2041446515 @default.
- W2000865549 cites W2042064080 @default.
- W2000865549 cites W2043002321 @default.
- W2000865549 cites W2043698546 @default.
- W2000865549 cites W2045363649 @default.
- W2000865549 cites W2045896850 @default.
- W2000865549 cites W2048529352 @default.
- W2000865549 cites W2054215548 @default.
- W2000865549 cites W2056825461 @default.
- W2000865549 cites W2057114534 @default.
- W2000865549 cites W2057833130 @default.
- W2000865549 cites W2057863409 @default.
- W2000865549 cites W2057894117 @default.
- W2000865549 cites W2058766124 @default.
- W2000865549 cites W2065205106 @default.
- W2000865549 cites W2065765236 @default.
- W2000865549 cites W2066692531 @default.
- W2000865549 cites W2068382974 @default.