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- W2000870159 abstract "Abstract The synthesis and characterization of Cu(5-Clsal)2(H2O)2 (5-Clsal = 5-chlorosalicylate) are reported. Characterization of the compound was based on elemental analysis, electronic and EPR spectra, and magnetic susceptibility measurement over a temperature range 93–239 K. An X-ray analysis of Cu(5-Clsal)2(H2O)2 was carried out, showing a polymeric chain of copper(II) atoms bridged by pairs of water molecules with Cu-O(bridge) bond lengths of 1.970(2) and 2.718(2)A. The coordination sphere about each copper(II) atom is completed (on the X-axis) by a trans-pair of unidentate 5-chlorosalicylate anions. The bridging oxygen atoms arrange a planar Cu2O2 rhombus. The relationship between degree of distortion and g-values from EPR spectra is also discussed." @default.
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- W2000870159 date "2001-04-01" @default.
- W2000870159 modified "2023-10-17" @default.
- W2000870159 title "CRYSTAL STRUCTURE, SPECTRAL AND MAGNETIC BEHAVIOR OF COPPER(II)(5-CHLOROSALICYLATO)2 (AQUA)2" @default.
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- W2000870159 doi "https://doi.org/10.1080/00958970108022611" @default.
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