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- W2000872419 abstract "We solve the inhomogeneous Ornstein–Zernike equation for the pair correlation functions together with the Lovett–Mou–Buff–Wertheim equation for the density profiles for charged hard spheres in the vicinity of a charged hard wall. This constitutes the so-called primitive model of the electric double layer. In this article, we consider 2-1 electrolytes (doubly charged positive ions and singly charged negative ions) near both positively and negatively charged surfaces. We use the hypernetted chain approximation to close the Ornstein–Zernike equation. Except for very high surface charge densities and low bulk concentrations, we obtain excellent agreement with the Monte Carlo data." @default.
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- W2000872419 date "1989-05-15" @default.
- W2000872419 modified "2023-10-16" @default.
- W2000872419 title "The primitive model of the electric double layer: Nonsymmetric electrolytes" @default.
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- W2000872419 doi "https://doi.org/10.1063/1.456381" @default.
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