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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000872427> ?p ?o ?g. }

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• W2000872427 abstract "Reaction of methylaluminium bis(2,6-di-tert-butyl-4-methylphenoxide) (MAD), 1, with alkyllithium reagents, R′Li (R′=Me, n-Bu or t-Bu), yields the solvent-dependent products lithium bis(2,6-di-tert-butyl-4-methylphenoxide)-THF complex, 2·THF, lithium dimethylbis(2,6-di-tert-butyl-4-methylphenoxide)aluminate, 3, a new type of lithium aluminate in which the lithium centre is stabilised by very short agostic Li⋯H(t-Bu) interactions, and tris(alkyl)aluminium. The observation of these products suggests an explanation for the tendency of α,β-unsaturated ketones to undergo conjugate (rather than 1,2-) addition in the presence of MAD and organolithium reagents." @default.
• W2000872427 created "2016-06-24" @default.
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• W2000872427 date "1999-01-01" @default.
• W2000872427 modified "2023-10-14" @default.
• W2000872427 title "Towards an understanding of the conjugate addition of organolithium reagents to α,β-unsaturated ketones: the isolation and solid-state structure of a monomeric lithium aluminate with very short agostic Li⋯HC interactions" @default.
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• W2000872427 doi "https://doi.org/10.1016/s0022-328x(98)00876-6" @default.
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