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- W2000878247 abstract "Abstract α‐(Phenyltelluro)esters 2 reacted with electron‐rich alkenes 3 in the presence of a catalytic amount of azobisisobutyronitrile (AIBN) as an initiator to give the corresponding addition products 4 . This carbotelluration of alkenes proceeded via a radical chain mechanism involving the bimolecular homolytic substitution (S H 2 ) reaction on tellurium as the key step, wherein tellurium plays an important role in a kinetic fashion to realize the rapid group transfer process resulting in suppressing the competing olefin polymerization. © 2011 Wiley Periodicals, Inc. Heteroatom Chem 22:518–522, 2011; View this article online at wileyonlinelibrary.com . DOI 10.1002/hc.20716" @default.
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- W2000878247 date "2011-01-01" @default.
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- W2000878247 title "Free radical addition of α-telluroesters to alkenes" @default.
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