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- W2000882557 abstract "A nuclear magnetic resonance study of 85Rb, 87Rb, and 19F in paramagnetic RbMnF3 is reported. The measured shifts of the rubidium nuclear resonances are the first reported for the case of an alkali nucleus in the paramagnetic XMF3 perovskite compounds (X = Na, K, Rb, Cs; M = Mn, Ni, Co). The shift for rubidium is in the opposite direction from that expected from a 5s contact hyperfine interaction. The isotropic hyperfine interaction of the fluorine indicates the presence of 0.51% unpaired 2s spins in the F— orbitals from each Mn+ + neighbor; this result is in good agreement with previous work for the F— resonances in these paramagnetic materials. The anisotropic shift of the F— resonance was examined in a powder sample and a 2p hyperfine coupling coefficient obtained." @default.
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- W2000882557 date "1965-06-01" @default.
- W2000882557 modified "2023-10-09" @default.
- W2000882557 title "Nuclear Magnetic Resonance in RbMnF<sub>3</sub>" @default.
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- W2000882557 doi "https://doi.org/10.1063/1.1695841" @default.
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