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- W2000883330 abstract "In this paper the Raman spectrum of liquid C2F6 in the spectral region 250–1500 cm−1 is presented. Data on six fundamental Raman bands of C2F6 are obtained. Doublets are observed in the spectral regions of the ν1 (A1g) (1416.3 cm−1, 1425.0 cm−1) and ν7 (Eg) (1221.9 cm−1, 1239.7 cm−1) fundamental bands. The structure of these bands is explained in terms of the Fermi resonances of ν7 ∼ (2ν8) ∼ (ν6 + ν11) (Eg) and ν1 ∼ (2ν6) (A1g) states. The values of the cubic potential energy constant K166 = 7.7 (2) cm−1 and the effective matrix element of a threefold interaction Weff = 8.5 (5) cm−1 were derived from the simultaneous processing of the doublet parameters in the Raman spectrum of liquid C2F6 and in the IR spectrum of C2F6 in liquid N2." @default.
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- W2000883330 date "2015-07-01" @default.
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- W2000883330 title "Fermi resonances in the vibrational spectrum of perfluoroethane" @default.
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- W2000883330 doi "https://doi.org/10.1016/j.molstruc.2015.02.059" @default.
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