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- W2000890706 abstract "The barrier to methyl rotation is exceptionally small in solid 4-methylpyridine, resulting in unusual properties. Earlier inelastic neutron scattering work concluded that the hindering potential has sixfold symmetry. This question is re-examined and a simpler spectrum found, indicative of the more normal threefold potential. A single tunnel peak at 0.5 meV broadens without shifting as the temperature is raised from 4 to 15 K. The absence of shift is discussed in the context of two different explanations for the shift normally observed with more strongly hindered methyl groups." @default.
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- W2000890706 date "1987-11-01" @default.
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- W2000890706 title "The symmetry of the methyl hindering potential and the temperature independence of the tunnel frequency in 4-methylpyridine" @default.
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- W2000890706 doi "https://doi.org/10.1016/0009-2614(87)85012-1" @default.
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