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- W2000893134 abstract "The reaction of the anion [Fe4(CO)13]− with AuClPR3 (R = Et, Ph) yields an anion which upon protonation gives the cluster Fe4AuC(H)(CO)12(PR3). This complex is reversibly deprotonated in the presence of base and the resultant anion upon treatment with AuClPR3 (R = Et, Ph) gives Fe4Au2C(CO)12(PR3)2; the formation of the latter involves attack at the carbido centre by the gold phosphine group. Both neutral carbido species were characterised by single-crystal X-ray analyses." @default.
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- W2000893134 date "1982-05-01" @default.
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- W2000893134 title "Syntheses and structural characterisations of some novel mixed-metal iron-gold carbido clusters; X-ray crystal structures of Fe4AuC(η-H)(CO)12(PPh3) and Fe4Au2C(CO)12(PEt3)2" @default.
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- W2000893134 doi "https://doi.org/10.1016/s0022-328x(00)92900-0" @default.
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