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- W2000894247 abstract "Calculations of the vibrational and dissociation transition probabilities are made for N2-N2 and N2-N collisions by means of a semiclassical N-state approximation. The flaws in previous techniques are reviewed, with special attention given to the prediction of overtones. The method presented ignores the effects of molecular rotation and employs a revised extended Rydberg intermolecular potential to describe diatom-diatom and diatom-atom collisions. The collision velocities investigated exhibit probabilities of less than unity by means of the N-state method. The continuum is quantized to treat dissociation, and the collision results demonstrate probability enhancements for V-V-T transitions in both bound-bound and bound-free transitions. The technique is of particular interest for the theoretical modeling of reentry flows such as those encountered in aerobraking maneuvers." @default.
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- W2000894247 date "1991-06-24" @default.
- W2000894247 modified "2023-09-23" @default.
- W2000894247 title "Vibrational relaxation and dissociation in nitrogen" @default.
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- W2000894247 doi "https://doi.org/10.2514/6.1991-1370" @default.
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