FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000895924> ?p ?o ?g. }

• W2000895924 endingPage "918" @default.
• W2000895924 startingPage "911" @default.
• W2000895924 abstract "Lignins, the aromatic biopolymers present in all vascular plant cell walls, may embody as many as 10 different linkages between the constituent (p-hydroxyphenyl)propane residues. The final step in lignin biosynthesis has traditionally been thought to involve the random coupling of radical intermediates produced during the dehydrogenative polymerization of monolignol precursors. However, the enzyme-catalysed dehydropolymerization of coniferyl alcohol in homogeneous solution has now been found to be strongly affected by small quantities of macromolecular lignin components. Under these circumstances, when the radical concentrations remained low, the molecular weight distributions of the dehydropolymerisates formed with horseradish peroxidase and H2O2 exhibited dramatic increases in the populations of the largest species. The phenomenon was not suppressed by prior methylation of the aromatic hydroxyl groups on the causative lignin macromolecules—which, therefore, were able to promote the formation of large covalent species from the monolignol without direct participation in radical coupling. If operative in lignifying tissues, such an effect could provide the organization necessary for replicating sequences of interunit linkages along macromolecular lignin chains. In this regard, the enzyme-catalysed dehydropolymerization of coniferyl alcohol would display the character of a typical template polymerization reaction. © 1997 Elsevier Science Ltd. All rights reserved" @default.
• W2000895924 created "2016-06-24" @default.
• W2000895924 creator A5034764714 @default.
• W2000895924 creator A5082259466 @default.
• W2000895924 creator A5082285141 @default.
• W2000895924 date "1997-07-01" @default.
• W2000895924 modified "2023-10-14" @default.
• W2000895924 title "Dehydrogenative polymerization of conifery alcohol on macromolecular lignin templates" @default.
• W2000895924 cites W1930020125 @default.
• W2000895924 cites W1966043525 @default.
• W2000895924 cites W1969356297 @default.
• W2000895924 cites W1978047292 @default.
• W2000895924 cites W1984292206 @default.
• W2000895924 cites W1988263638 @default.
• W2000895924 cites W1990620283 @default.
• W2000895924 cites W2000213969 @default.
• W2000895924 cites W2005095742 @default.
• W2000895924 cites W2005430597 @default.
• W2000895924 cites W2007843757 @default.
• W2000895924 cites W2008007998 @default.
• W2000895924 cites W2036120920 @default.
• W2000895924 cites W2039508243 @default.
• W2000895924 cites W2047200585 @default.
• W2000895924 cites W2051263055 @default.
• W2000895924 cites W2061818319 @default.
• W2000895924 cites W2063907872 @default.
• W2000895924 cites W2064329397 @default.
• W2000895924 cites W2065484159 @default.
• W2000895924 cites W2071268213 @default.
• W2000895924 cites W2074967998 @default.
• W2000895924 cites W2075699668 @default.
• W2000895924 cites W2082321849 @default.
• W2000895924 cites W2093043248 @default.
• W2000895924 cites W2093757009 @default.
• W2000895924 cites W2117863422 @default.
• W2000895924 cites W2139687312 @default.
• W2000895924 cites W2153348392 @default.
• W2000895924 cites W2386651037 @default.
• W2000895924 cites W2487525569 @default.
• W2000895924 cites W2497824794 @default.
• W2000895924 doi "https://doi.org/10.1016/s0031-9422(97)00077-0" @default.
• W2000895924 hasPublicationYear "1997" @default.
• W2000895924 type Work @default.
• W2000895924 sameAs 2000895924 @default.
• W2000895924 citedByCount "52" @default.
• W2000895924 countsByYear W20008959242012 @default.
• W2000895924 countsByYear W20008959242013 @default.
• W2000895924 countsByYear W20008959242014 @default.
• W2000895924 countsByYear W20008959242018 @default.
• W2000895924 countsByYear W20008959242020 @default.
• W2000895924 countsByYear W20008959242022 @default.
• W2000895924 countsByYear W20008959242023 @default.
• W2000895924 crossrefType "journal-article" @default.
• W2000895924 hasAuthorship W2000895924A5034764714 @default.
• W2000895924 hasAuthorship W2000895924A5082259466 @default.
• W2000895924 hasAuthorship W2000895924A5082285141 @default.
• W2000895924 hasConcept C178790620 @default.
• W2000895924 hasConcept C180577832 @default.
• W2000895924 hasConcept C181199279 @default.
• W2000895924 hasConcept C185592680 @default.
• W2000895924 hasConcept C204389451 @default.
• W2000895924 hasConcept C2777676563 @default.
• W2000895924 hasConcept C2780678855 @default.
• W2000895924 hasConcept C2780753511 @default.
• W2000895924 hasConcept C2781052789 @default.
• W2000895924 hasConcept C44228677 @default.
• W2000895924 hasConcept C521977710 @default.
• W2000895924 hasConcept C553450214 @default.
• W2000895924 hasConcept C55493867 @default.
• W2000895924 hasConceptScore W2000895924C178790620 @default.
• W2000895924 hasConceptScore W2000895924C180577832 @default.
• W2000895924 hasConceptScore W2000895924C181199279 @default.
• W2000895924 hasConceptScore W2000895924C185592680 @default.
• W2000895924 hasConceptScore W2000895924C204389451 @default.
• W2000895924 hasConceptScore W2000895924C2777676563 @default.
• W2000895924 hasConceptScore W2000895924C2780678855 @default.
• W2000895924 hasConceptScore W2000895924C2780753511 @default.
• W2000895924 hasConceptScore W2000895924C2781052789 @default.
• W2000895924 hasConceptScore W2000895924C44228677 @default.
• W2000895924 hasConceptScore W2000895924C521977710 @default.
• W2000895924 hasConceptScore W2000895924C553450214 @default.
• W2000895924 hasConceptScore W2000895924C55493867 @default.
• W2000895924 hasIssue "5" @default.
• W2000895924 hasLocation W20008959241 @default.
• W2000895924 hasOpenAccess W2000895924 @default.
• W2000895924 hasPrimaryLocation W20008959241 @default.
• W2000895924 hasRelatedWork W199417122 @default.
• W2000895924 hasRelatedWork W2012622798 @default.
• W2000895924 hasRelatedWork W2032085175 @default.
• W2000895924 hasRelatedWork W2048333957 @default.
• W2000895924 hasRelatedWork W2136857652 @default.
• W2000895924 hasRelatedWork W2304509003 @default.
• W2000895924 hasRelatedWork W2738221582 @default.
• W2000895924 hasRelatedWork W2742330954 @default.
• W2000895924 hasRelatedWork W2887646832 @default.
• W2000895924 hasRelatedWork W4220992140 @default.
• W2000895924 hasVolume "45" @default.
• W2000895924 isParatext "false" @default.

• next