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• W2000904525 abstract "Reaction of N-ligated methylpalladium(II) alkoxide and aryloxide complexes [Pd(Me)(OR)(N ∼ N)] (R = Ph, CH(CF3)2; N ∼ N tmeda (N,N,N′,N′-tetramethylethylenediamine) or bpy (2,2′-bipyridyl)) with carbon monoxide produces the corresponding methylesters in high yields. The insertion takes place either into the PdMe bond (aryloxide complexes) or into the PdOR bond (alkoxide complexes). Methylalladium(II) methoxide complexes [Pd(Me)(OMe)(N∼N)] (N ∼ N = tmeda, bpy) have been generated in situ by aryloxide- or alkoxide-methanol exchange reactions for which the equilibrium constants have been determined. The bpy-ligated methylpalladium methoxide complex undergoes insertion of CO producing either a methylpalladium methoxycarbonyl complex [Pd(ME(CO2Me)(bpy)] at −60°C) or an acylpalladium methoxycarbonyl complex [Pd(COMe)(CO2Me)(bpy)] (at −25°C); both carbonylated species could be isolated nd characterized at low temperature." @default.
• W2000904525 created "2016-06-24" @default.
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• W2000904525 date "1996-06-01" @default.
• W2000904525 modified "2023-10-16" @default.
• W2000904525 title "Chemistry of diamino-ligated methylpalladium(II) alkoxides and aryloxides (Part II): methoxide formation and carbonylation reactions" @default.
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• W2000904525 doi "https://doi.org/10.1016/0022-328x(96)06171-2" @default.
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