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• W2000904726 abstract "Structures of Pd/zeolites immersed in solvents were measured by in situ X-ray absorption fine structure (XAFS). Systematic studies revealed that the selection of an appropriate support (USY-zeolite), thermal treatment temperature of USY, solvent (o-xylene), H(2) partial pressure (6%), and the use of a Pd amine complex affect the structure of Pd. As a result, we found that monomeric Pd can be obtained in the USY support with H(2) bubbling in o-xylene. The structural properties of Pd correlate well with its catalytic performance in the Suzuki-Miyaura coupling reactions; a very high TON of up to 11,000,000 was obtained over the monomeric Pd." @default.
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• W2000904726 date "2009-12-10" @default.
• W2000904726 modified "2023-10-10" @default.
• W2000904726 title "Highly Dispersed Pd Species Active in the Suzuki–Miyaura Reaction" @default.
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• W2000904726 doi "https://doi.org/10.1002/cphc.200900711" @default.
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