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- W2000905650 abstract "Electric field gradient (EFG) lattice sums for the vacancy-disordered and vacancy-ordered forms of maghemite were evaluated using a point charge model. The calculated EFGs produced a wide range of magnitudes and principal directions for the quadrupole interaction for both forms of maghemite. Small perturbations of the crystallographic parameters were shown to have a significant effect on the quadrupole shift. The effects observed were significant enough to show that quadrupole shifts should be considered when fitting the Mössbauer spectra of maghemite." @default.
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- W2000905650 date "2011-04-14" @default.
- W2000905650 modified "2023-09-27" @default.
- W2000905650 title "The effect of vacancy ordering on quadrupole shifts in Mössbauer spectra of maghemite" @default.
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- W2000905650 doi "https://doi.org/10.1088/0953-8984/23/17/176004" @default.
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